15N and 31P NMR Studies of Cyano[(Trialkyl/Triaryl)Phosphine]Gold(I) Complexes R3PAu13C15N

نویسندگان

  • M. Naseem Akhtar
  • Anvarhusein A. Isab
  • Abdul Rahman Al-Arfaj
  • Mohammed I. M. Wazeer
چکیده

been studied for R=Me, Et, i-Pr, and Ph. The reactions are studied by 15N and 31p NMR spectroscopy. Two 31p NMR resonances were observed for R3PAuCN and (R3P)2Au+ species. However, for the 15N NMR, only averaged resonances were observed for R3PAuC15N and Au(C15N)2" species except for Et3PAuC15N, where two resonances were detected.The R3PAu13C15N complexes have also been prepared where R= Me, Et, and Ph. Analysis of 31p NMR of R3PAu13C15N (where R=Me, Et and Ph yielded 2j(31p.13C) values as 120.71, 122.18 and 124.57 Hz and 3j (31p.15N) values as 3.62,

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عنوان ژورنال:
  • Metal-Based Drugs

دوره 1  شماره 

صفحات  -

تاریخ انتشار 1994